Taymour Eslamkish; Milad Kurdi
Abstract
Introduction: Peat is an organic soil which is formed by the accumulation of decayed vegetative matter that have formed in areas of poor water drainage. The mineral components of peat are derived from inorganic matter contained in sediments and by adsorption from groundwater. The inorganic (mineral) ...
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Introduction: Peat is an organic soil which is formed by the accumulation of decayed vegetative matter that have formed in areas of poor water drainage. The mineral components of peat are derived from inorganic matter contained in sediments and by adsorption from groundwater. The inorganic (mineral) fraction of peat usually includes only 2–10 Percent of its dry weight, but for highly decomposed peats can increase to about 60 percent of dry weight. Thin sections of peat reveal detailed information of composition, structure, fabric and particularly pore properties which influence water retention and movement. Peat is a concentrated form of soil organic matter which has environmental, industrial, agricultural and medical uses that range from sustaining the productive capacity of agricultural land. This study has been focused on micromorphological and mineralogical properties of Suteh peat swamp forest (PSF) in Golestan province, north of Iran. Golestan province is the third largest cereal producer in Iran but scarcity of water and salinity are most important major problems in this area. This area has been covered by almost 400,000 hectares of forests. Suteh PSF has been chosen as a swamp that contains organic and inorganic matters. As the inorganic composition of peat varies considerably from region to region, study of mineralogical and micromorphological of Suteh PSF can be useful in order to identification of Golestan province peat swamps. Since the early 1990s, micromorphological studies have become increasingly popular in the analysis of lakeside settlements. The evaluation of soils considers thin-section observations, macromorphological features, and laboratory data. Micromorphological analyses allow the characterization of natural and anthropogenic sediments, which in turn enables the determination of sedimentary processes and depositional environment.
Materials and Methods: This study was carried out in April 2014. The samples were collected from zero to 40 cm depth of swamp areas, within a 10 cm radius. At each sampling station, peat samples were collected with a trowel. The area included the north side of the Alborz Mountains and extended northward to the township of Gorgan. The altitude was approximately 950–2000 m a.s.l. According to the Gorgan Natural Resources Bureau report, Suteh is temperate to semi-arid on the Emberger climate diagram. To achieve the purpose, samples were dried and prepared based on standard methods. These studies were carried out using polarized microscope on thin sections and polished section at the Mineralogy Laboratory of the Amirkabir University of Technology.To prepare thin sections for microscopy studies, samples with polyester, cobalt oxide and hardener have been combined. Polyester formed the matrix of the section and hardener (HCl + H2O2) has been used to reduce a hard time getting. Cobalt oxide has been used as a catalyst between them. The samples have been kept tight in special containers. Due to the presence of organic matter, much time was needed to harden them. The samples were dried and tightened for 20 days. Then, the samples were polished by various polishers (No. 400, 600, 800, 1000 and 2000). After that, they were polished for 20 minutes by the suspension of alumina (Al2O3 + H2O).
Results and Discussion: The coarse material that formed groundmass were composed of quartz, muscovite, orthoclase, calcite, opacity pyroxene biotite and opaque minerals. Some flakes of muscovite, pyroxene and biotite showed weathering. Fe–Mn components were most common in opaque minerals. Quartz crystals were seen in abundance in most sections. Weathered surface of orthoclase was seen in some sections. The large biotite crystals were seen at different sections with pleochroism light brown to dark brown. Root and other organ residues in varieties states of decomposition were observed in some sections. Fragments of organ and tissue residues were rather few and found mostly in the surface of Suteh PSF. For detailed assessment of opaque minerals, one of the grains was selected and analyzed. The weathering of minerals showed the normal stability trend, i.e. quartz >muscovite>biotite. Biotite loses its pleochroism and alters first to a mica-vermiculite interstratified clay mineral. Polished sections study showed Fe components were the major and dominate in the sections.
Conclusions: Thin sections results showed the samples contained quartz, orthoclase, muscovite, biotite, calcite, opacity pyroxene and opaque minerals. Polished sections results revealed that Fe components were most common in opaque minerals in the sections. Micromorphological study showed root and other organ residues in Suteh PSF that this showed this soil composed of a mixture of organ residues and organic material.
salar rezapour; H. Azhah
Abstract
Introduction: Human activities such as intensive cultivation and land use changes alter nutrients fluxes (mainly iron) and mineralogy in soil and terrestrial ecosystems. Iron is an essential element for plants and microorganisms and its solubility is controlled by stable hydroxides, oxyhydroxides, and ...
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Introduction: Human activities such as intensive cultivation and land use changes alter nutrients fluxes (mainly iron) and mineralogy in soil and terrestrial ecosystems. Iron is an essential element for plants and microorganisms and its solubility is controlled by stable hydroxides, oxyhydroxides, and oxides. In general, parent material, climate, and landscape position are the major factors that accelerate the weathering of the minerals and rocks containing Fe in the regional scale. However, long-term cultivation and intensified agriculture may be the dominant attributes of modifications in soil properties like Fe compounds mainly in arid and semiarid regions, where the irrigational and agricultural practice is current over long-term periods. Although substantial data is documented on Vertisols properties, few studies are available to assess the effects of long-term continuous cultivation on the characteristic and distribution of iron oxides and their mineralogy, mainly in calcareous environments.
Materials and Methods: This study was conducted in the Piranshahr - Pasvah area (36° 46 to 36° 50 N and 45° 09 to 45° 50 E, 1500 m above sea level), West Azarbaijan Province, northwest of Iran. Six soil profiles belonging to three subgroups of Vertisols order (Chromic Calcixererts, Typic Haploxererts, and Typic Calcixererts) were described and sampled from the cultivated soils and similar soils from the nearby uncultivated region as grassland. Soil samples were air-dried and passed through a 2-mm mesh sieve before the analysis. Soil analysis included particle-size distribution, pH and electrical conductivity (EC), soil organic carbon (SOC), calcium carbonate equivalent (CCE), cation exchange capacity (CEC), the determination of iron oxides forms and mineralogical composition. Free or pedogenic Fe oxides (Fed) including crystalline, poorly crystalline, and organically bound Fe were extracted by dithionite–citrate–bicarbonate (DCB) method. Poorly crystalline and organically bound Fe (Feo) were extracted using 0.2 M ammonium oxalate (AO). Organic complex of Fe (Fep) was extracted by 0.1 M Na-pyrophosphate at pH 10. All Fe oxide forms were determined using atomic absorption spectrometry. The difference between DCB-Fe and AO-Fe was considered as an estimation of crystalline Fe oxides form.
Results and Discussion: The results showed that long-term cropping caused a considerable drop in organic carbon and calcium carbonates along with a noticeable rise in the values of clay and cation exchange capacity as a result of accelerated alteration by farming activities and interactions between the used irrigation water and soils receiving it. Long-term cultivation improved the amount of Fed and Fecry (crystalline Fe) from 1 to 64% and 44 to 90%, respectively, than those of uncultivated soils which can be explained in some pathways: (1) accelerated weathering of Fe-bearing minerals (such as biotite, chlorite, feldspars, amphibole, and pyroxene) in the cultivated soils and (2) the higher temperature condition and the more number of wetting–drying cycles in the cultivated soils compared to the uncultivated soils. Despite the fact that long-term cultivation caused a significant decrease in organic matter, a pronounced increase in organic complex of Fe with the range of 19 to 61% was recorded with farming practices. Such pattern can be contributed to the chemistry of organic matter and the presence of more stable fraction (passive fraction) of soil organic matter in the cultivated soils. The XRD patterns of primary Fe-bearing minerals (such as amphibole, pyroxene, and feldspar) had less intense in the cultivated soils compared to those of the adjacent uncultivated soils, indicating that probably cultivation promoted the instability and weatherability of Fe-bearing minerals as well as the loss of Fe from the minerals. In contrast, the X-ray reflections of secondary Fe-oxide minerals such goethite appeared to be higher, sharper and intense by long-term cropping, suggesting that agricultural practices also promoted the crystallization of the soil Fe oxides. Compared to the uncultivated soils, long-term agricultural practices caused some changes in X-ray reflections of chlorite, illite, and smectite.
Conclusions: The results showed that the weathering of Fe-bearing minerals and layer silicates, as well as the production of Fe oxide forms were promoted under long-term continuous cropping. Under cultivation, a pronounced increase in Fe-oxide forms, particularly Fed and Fecry, was recorded for the most of the examined soils which can be associated with the combined effects of increased soil temperature and moisture content from irrigation and farming practices. As emphasized, the combined effects of increased compounds from agricultural input (such as chemical and organic fertilizers, the compound of irrigation water, and moldboard tillage) as well as increased precipitation from irrigation interacted to create conditions for: (1) more intense the weathering of Fe-bearing minerals and (2) the more production of iron oxides forms in the cultivated soils.
R. Beitlefteh; A. Landi; S. Hojati; Gh. Sayyad
Abstract
Introduction: Recently, air pollution due to the occurrence of dust storms is one of the worst environmental problems in Western and Southwestern Iran, especially the Khuzestan Province (12, 13). According to the reports of the Meteorological Organization of Iran the average number of dusty days in the ...
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Introduction: Recently, air pollution due to the occurrence of dust storms is one of the worst environmental problems in Western and Southwestern Iran, especially the Khuzestan Province (12, 13). According to the reports of the Meteorological Organization of Iran the average number of dusty days in the cities of Ahvaz and Abadan in the Khuzestan Province reaches 68 and 76 days each year, respectively (6). Previous studies have shown that the yearly damage costs of wind erosion and occurrence of dust storms in the Khuzestan Province reach about 30 Billion Rials (5). However, very few studies have been conducted on the characterization of dust particles and also the identification of their origins in Iran, especially the Khuzestan Province. Hojati et al. (10) reported that dust deposition rate, mean particle diameter, and concentration of soluble ions in samples taken from Isfahan and Chaharmahal and Bakhtiari Province decrease with altitude, with a significantly lower gradient in periods with dust storms. They reported three factors that control the rate and characteristics of dust deposited across the study transect: 1) climatic conditions at the deposition sites, 2) distance from the dust source, and 3) differences between local and transboundary sources of dust.Therefore, this study was conducted to investigate the effects of dust storms on deposition rate, mineralogy and size distribution patterns of dust particles from twelve localities around the Houralazim lagoon.
Materials and Methods: Dust samples were collected monthly during a 6 month experiment from August 2011 to February 2012. In order to differentiate between the contribution of dust production by local soils and other sources, surface soils were also sampled from the vicinity of the dust sampling sites. The collection trays were made of a glass surface (100 × 100 cm) covered with a 2 mm-sized PVC mesh on the top to form a rough area for trapping the saltating particles (Fig. 2). Dust samples were collected by scraping materials adhered to the glass trays using a spatula. All the trays were wet cleaned before the next collection. The collected dust and soil samples were examined for their grain size distribution using a Malvern Hydro 2000g laser particle size analyzer, as well as their mineral compositions by a Philips PW1840 X-ray diffractometer and a LEO 906 E transmission electron microscope (TEM).
Results and Discussion: The results showed that wind speed and direction patterns during the periods with dust storms and those without dust storms were different. Accordingly, in periods with dust storms (3, 5 and 6) the contribution of winds with speeds greater than 11.1 m/sec, especially from the Northwest direction, increased when compared with those from the periods without dust storms (1, 2 and 4). Besides, the direction of prevailing winds in periods without dust storms were mainly from the West and the Northwest. However, in periods with dust storms East-directed winds were also observed (Fig. 3). These show that the source areas of dust particles in these periods are probably different. The results also illustrated that the average amount of deposited particles in the periods with dust storms (12.5 g m-2 month-1) was considerably more than that of the periods without dust storms (7.5 g m-2 month-1) (Figs. 4 and 5). The difference in dust deposition rate between periods having dust storms and those without dust storms seems to be due to dust input from a source outside the study area. Particle size distribution analysis showed that dust particles collected from the study area in both periods (with and without dust storms) are mainly silt-sized particles. This fraction contributes to 60 to 76 % of the particles collected from periods without dust storms and 66 to 82 % of particles affected by dust storms (Table 2). The results also imply that in both periods (with and without dust storms), dust particles collected from the study area had a bimodal distribution pattern which suggests mixing of settled particles from different sources and/or deposition processes (Fig. 6). Mineralogical composition of dust particles were collected from both periods (with and without dust storms) and those from the soils contained quartz, calcite, feldspar, halite, dolomite and palygorskite (Figs. 7 and 8). Moreover, the TEM images of dust particles collected in periods with dust storms showed higher amounts of palygorskite than in periods without dust storms (Fig. 9).
Conclusion: The similarity in the physical properties of local soils and deposited particles of the periods with and without dust storms implies that the contribution of local soils and sediments in producing dust particles is high. However, it seems that in periods with dust storms the contribution of a transboundary origin such as Iraqi arid lands in producing dust particles increases.
R. Karimi; M.H. Salehi; Z. Mosleh
Abstract
Nowadays, changing the rangelands to agriculture and garden is common. To investigate the impact of land use change on the soils type and clay mineralogy, four land uses including rangeland with poor vegetation, agricultural land, new and old apple orchards were selected in Safashahr area, Fars province. ...
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Nowadays, changing the rangelands to agriculture and garden is common. To investigate the impact of land use change on the soils type and clay mineralogy, four land uses including rangeland with poor vegetation, agricultural land, new and old apple orchards were selected in Safashahr area, Fars province. In each land use, three soil profiles were excavated and described and one profile was considered as representative. After required physical and chemical analyses, they were classified according to Soil Taxonomy (ST) and the World Reference Base for Soil Resources (WRB). Selected surface and subsurface samples were also collected for clay mineralogy studies. Results showed that changing land use did not have significant effect on soil type and clay minerals and all soils consist of mica, chlorite, smectite, kaolinite and mixed layer minerals. Results demonstrated that ST is more efficient compared to WRB to classify the studied soils.