Clay Mineralogy of Soils on Quaternary Sediment in Northeast of Urmia

Document Type : Research Article

Authors

• Parisa Farzamnia
• Shahram Manafi
• Hamidreza Momtaz

Urmia University

https://doi.org/10.22067/jsw.v30i6.45040

Abstract

Introduction: Minerals are one of the main components of soils which play different roles in the soils. Minerals make up about 50% of the volume of most soils. They provide physical support for plants, and create the water- and air-filled pores that make plant growth possible. Mineral weathering releases plant nutrients which are retained by other minerals through adsorption, cation exchange, and precipitation. Minerals are indicators of the amount of weathering that has taken place, and the presence or absence of particular minerals gives clues to how soils have been formed. The physical and chemical characteristics of soil minerals are important consideration in planning, constructing, and maintaining of buildings, roads, and airports. Clay minerals can be used for understanding of soil formation, optimum management of dry and wet lands and interpretation of paleo environments. Moreover, clay minerals can provide some valuable information such as the origin of sediments, transportation and precipitation of sediments and also some information about intercontinental weathering regimes. Quaternary sediments have occupied most of the agricultural and natural resources of Urima plain and recognition of mineralogical of these soils is essential to optimum and stabile use of these soils. Additionally, caly mineralogical investigation can provide some information about the intensity of weathering processes and climate change in this area. Thus, in this study clay minerals of quaternary sediments in northeast of Urmia and the mechanisms of their formation and also tracing probable climate change in this area were investigated.
Materials and Methods: This study was performed in theUrmia plain in west Azerbaijan Province. The study area is located on quaternary sediments and physiographically, this area is a part of a river alluvial plain with the gentle slope toward Urmia Lake. The mean annual precipitation and temperature of this area are 345.37 mm and 10.83 °C respectively and the soil moisture and temperature regimes are dry xeric and mesic respectively. In this study, eight soil profiles in quaternary sediments were dug and sampled and the morphological, physical, chemical and mineralogical properties were determined using standard methods.
Results and Discussion: According to the results, Illite, smectite, Kaolinite, chlorite, vermiculite and hydroxy interlayer vermiculite (HIV) were the dominant clay minerals in these soils. The origin of illite, chlorite and kaolinite were related to inheritance from parent material. Regarding to the present of some smectite in the parent material of these soils, some of smectites have been inherited from parent material. Nevertheless it seems that, the most of smectites in these soils have pedogenic origin. Based on mineralogical results and trends variation of smectite and illite along studied profiles, we concluded that some of smectites in these soils have been formed from illite transformation. In profiles 4 and 6, regarding to low depth water table and consequently poor drainage, high pH and high values of calcium and magnesium cations, provide suitable conditions for the neoformation of smectit and so, some of smectites have been formed via neoformation from soil solution. In these soils, vermiculites were pedogenic and have been formed during transformation of illite to smectite. Small amounts of hydroxy interlayer vermiculites were present in buried horizons and regarding that they were not present in parent material, it might be because these minerals are pedogenic and have been formed in a past wetter climate. The transformation of illite to smectite in lower horizons needs high moisture and regarding to recent semiarid climate of study area, the suitable amount of moisture for this transformation, especially in lower depths and also in buried horizons, is not present. Thus, it seems the transformation of illite to smectite in lower depths and buried horizons has been taken place in a wetter past climate. So we concluded that smectite and hydroxy interlayer vermiculite are evidences of a wetter past climate in this area.
Conclusion: In this study the origin of smectite in buried horizons was related to transformation of illite. According to high moisture condition which is necessary for the weathering of illite, the occurrence of this process related to more humid climate of the past. Additionally, the presence of hydroxy interlayer vermiculites was related to previously wetter climate as well. So results of this study can be used for recognition of climatic change in the study area.

Keywords

• Buried horizon
• Climate change
• Neoformation
• Smectite

20.1001.1.20084757.1395.30.6.20.0

References

1- Abbaslou H., and Abtahi A. 2007. Origin andDistribution of Clay Minerals in Calcareous,Gypsiferous, Saline Soils and Sediments ofBakhtegan Lake Bank, Southern Iran. Iran AgriculturalResearch, 25:81-86.

2- Azizi P., Mahmoodi S.H, and Torabi H. 2011. Morphological, Physico-Chemical and Clay Mineralogy Investigation on Gypsiferous Soils in Southern of Tehran, Iran. Middle-East Journal of Scientific Research, 7:153-161.

3- Biscaye P.E. 1965. Mineralogy and sedimentation of reacent deep-sea clay in Atlentic Ocean and adjacent seas and ocean, Geol.soc.AM.Bull.76:803-831.

4- Bockheim J.G., and Gennadiyev A. N. 2000. The role of soil-forming processes in the definition of taxa in Soil Taxonomy and the World Soil Reference Base. Geoderma, 95:53–72.

5- Bonifacio E., Falsone G., Simonov G., Sokolova T., and Tolpeshta I. 2009. Pedogenic Processes and Clay Transformations in Bisequal Soils of the Southern Taiga Zone. Geoderma, 149: 66–75.

6- Borchardt G. 1989. Smectites. p. 675-729. In Dixon J. B., and S. B. Weed. (Ed.). Minerals in soil environment. 2nd ed. SSSA. Madison, WI.

7- Costantini E. A.C., and Damiani D. 2004. Clay minerals and the development of Quaternary soils in centralItaly. Revista Mexicana de CienciasGeologicas, 21:144-159.

8- Deer W.A., Howie R.A., and Zussman J. 1971. Rock forming minerals, sheet silicates, Vol. 3, Longman Publication.270 p.

9- Dixon J.B., and Weed S.B. 1989. Minerals in Soil Environments. 2nd (Ed.). Soil ScienceSociety of America Journal. Madison Wisconsin. USA.

10- Egli M., Mirabella A., Sartori G., and Fitze P. 2003. Weathering Rates as a Function of Climate: Results from a Climosequence of the Val Genova (Trentino, Italian Alps). Geoderma, 111:99–121.

11- Ehrmann W., Setti M., and Marinoni L. 2005. Clay minerals in Cenozoic sediments off Cape Roberts (McMurdo Sound, Antarctica) reveal the paleoclimatic history.Palaeogeography, Palaeoclimatology, Palaeoecology, 229:187- 211.

12- Fanning D.S., Kermaidas V.I., and EL-Desoky M.A. 1989. Micas. p. 551–635. In Dixon J.B., and S.B. Weed. (Ed). Minerals in soil environment. 2nd ed. SSSA, Madison. WI.

13- Farzamnia P., Manafi Sh., and Momtaz H.R. 2013. The study of physico-chemical properties of soils formed on Quaternary sediments in some lands of Urmia Plain. P. 1-4. In S.S. Hashemi (ed.) Proceeding of the national Congress of soil and Sustainable agriculture, 17 Mar. 2013. Malayer, Iran.

14- Galan E. 2006. Genesis of Clay Minerals. Elsevier Ltd.

15- Ghergherechi S., and Khormali F. 2008. Distribution and Origin of Clay Minerals Influenced by Ground-water Table and Land Use in South-west Golestan Province. Journal of Agricultural Science and Natural Resource, 15: 18-30.

16- Graham R.C., and ƠGreen. 2010. Soil mineralogy trends in California landscapes. Geoderma, 154:418-437.

17- Horiuchi K., Minoura K., Hoshino K., Oda T., Nakamura T., and Kawai T. 2000. Palacoenvironmental history of Lake Balkal during the last 23000 years. PalaeogeographyPalaeoclimatologyPalaeoecology, 157:95-108.

18- Khormali F., and Abtahi A. 2003. Origin and distribution of clay minerals in calcareous arid andsemi-arid soils of Fars Province, southern Iran. Clay minerals, 38:511-527.(in Persian with English abstract)

19- Khormali F., and Ghorbani R. 2010. Origin and distribution of clay minerals in eastern climatic region of Golestan Province. Journal of Agriculture Science and Natural Resource, 16:6. (In Persian).

20- Kiani F., Jalalian A., Pashaee A., and Khademi H. 2006. The study of clay minerals in a losse- paleosol in the Pasang region of Golestan province. Iranian Journal of Crystallography and Mineralogy,14:2. 395-412. (In Persian).

21- Kittrick J.A., and Hope E.W. 1963. A procedure for the particle size separation of soils for X-Ray diffraction analysis. Soil Science Society of America Journal, 96:312-325.

22- Laurence Q., Anatja S., Bertrand L., and Sophie C. 2011. Lessivage as a major process of soil formation: A revisitation of existing data. Geoderma, 167:135-147.

23- Mahjoory R.A. 1975. Clay mineralogy, physical and chemical properties ofsome soils in arid regions of Iran. Soil Science Society of America Journal, 39:1157-1164.

24- Manafi SH. 2010. Mineralogical Evidence of Climate Change in some Semiarid Soils of SouthernUrmia, Iran. Soil science Agrochemistry and Ecology, 4:17-24.

25- Mehra O.P., and Jackson M.L. 1960. Iron oxide removal from soils and clays by a dithionite citrate system with sodium bicarbonate. Clays and Clay Minerals, 7:317-327.

26- Mirkhani R., Shabanpour M., and Saadat S. 2005. Using particle-size distribution and organic carbon percentage to predict the cation exchange capacity of soils of Lorestan province. Tehran, Iran. Journal of Soil and Water Science, 19:235-242. (in Persian with English abstract)

27- Moore D. M., C. Robert., Jr., and Reynolds. 1989. X-Ray diffraction and the identification and analysis of clay minerals. 2nd ed., Oxford university press. New York.

28- O'Geen A.T., Hobson W.A., Dahlgren R.A., and Kelly D.B. 2008. Evaluations of soil propertiesand hydric soil indicators for vernal pool catenas in California. Soil Science Society of America Journal, 72:727–740.

29- Pal D.K., Bhattacharyya T., Sinha R., Sirvastava P., Dasgupta A.S., Chandran P., Ray S.K., and Nimje A. 2011. Clay minerals record from Late Quaternary drill cores of the Ganga Plains and their implications for provenance and climate change in the Himalayan foreland. Palaeogeogr. Palaeoclimatol. Palaeoecol, 356-357:27-37.

30- Perederij V.I. 2001. Clay mineral composition and paleoclimatic interpretation of the Pleistocene depositso Ukraine. Quaternary International, 76/77:113-121.

31- Perkins D. 2002. Mineralogy. 2nd (Ed.). Prentice Hall. p. 474.

32- Peter M., Jacobs M., Michael E., Konen B., and Curry B. 2009. Pedogenesis of a catena of the Farmdale-Sangamon Geosol complex in the north central United States. Paleogeog. Paleoclim. Paleoecol, 282:119-132.

33- Schnyder J., Gorin G., Soussi M., Baudin F., and Deconinck J.F. 2005. Enregistrement de la variation climatique au passage Jurassique/Cretace sur la marge sud de la Tethys: mineralogie des argiles et palynofacies de la coupe du JebelMeloussi (Tunisie Centrale, Formation Sidi Kralif). Bulletin de la SocieteGeologique de France, 176:171–182.

34- Soil and Water Research Institute of Iran. 1989. Land capabilitymap of Western Azerbaijan in 1:250000 scale, sheet No. II. Soil and Water Research Institute of Iran publication, Tehran, Iran.

35- Soil Survey staff. 2003. Soil Survey Manual. Soil Conservation Service. U.S. Dept of Agriculture. Handbook 18.

36- Soil Survey Staff. 2014. Keys to Soil Taxonomy. 12th (Ed.). USDA. SCS. Agric. U.S. Gov. Print office. Washington. D. C.

37- Solotchina E. P., Prokopenko A.A., Vasilevsky A.N., Garshin V.M., Kuzmin M.I., and Williams D.F. 2002. Simulation of XRD patterns as an optimal technique in bottom sediments of Lake Baikal. Calys and Clay Minerals, 37:105-119.

38- SoltaniSisi G. 2005. Geological map of Iran, 1:100000 series, sheet No, 5065. Geological survey and mineral Exploration of Iran.

39- Thiry M. 2000. Palaeoclimatic interpretation of clay minerals in marine deposits; an outlook from the continental origin. Earth-Science. Review, 49:201–221.

40- USDA-NRCS. 2004. Soil Survey Laboratory Methods Manual. Soil survey investigations. Report No, 42. Version, 3.

41- Webster K. L., Creed I. F., Beall F. D., and Bourbonnièr R.A. 2011. A topographic template for estimating soil carbon pools in forested catchments. Geoderma, 160:457-467.