ناپویاسازی کادمیم در خاک با استفاده از نانوذرات مگنتیت تثبیت‌شده با سدیم دودسیل سولفات

نوع مقاله : مقالات پژوهشی

نویسندگان

• احمد فرخیان فیروزی ¹
• محمدجواد امیری ²
• حسین حمیدی فر ³
• مهدی بهرامی ²

¹ دانشگاه شهید چمران اهواز

² دانشگاه فسا

³ دانشگاه شیراز

https://doi.org/10.22067/jsw.v31i1.50713

چکیده

کادمیم یکی از فلزات سنگین است که به خاطر اثرات سمی بالقوه آن بر فعالیت و ترکیب موجودات زنده خاک، در چند دهه گذشته بسیار مورد توجه قرار گرفته است. تثبیت فلزات سنگین با استفاده از اصلاح کننده ها، روشی ساده و سریع برای کاهش گسترش آلودگی فلزات سنگین محسوب می شود. هدف از این پژوهش سنتز نانوذرات مگنتیت (Fe3O4) تثبیت شده با سدیم دودسیل سولفات (SDS) و بررسی اثر درصدهای مختلف آن (از صفر تا 10 درصد) بر شکل های مختلف کادمیم در خاک آلوده شده با 1000 میلی گرم کادمیم بر کیلوگرم با روش عصاره گیری دنباله ای تسیر بود. نتایج نشان داد غلظت کادمیم در شکل های محلول و کربناتی با افزایش درصد نانوذرات کاهش یافت. بیشترین میزان کاهش غلظت کادمیم در تیمار 10 درصد نانوذره (80 درصد در شکل محلول و 28 درصد در شکل کربناتی نسبت به تیمار شاهد) مشاهده شد. غلظت کادمیم متصل به شکل اکسیدها با افزایش درصد نانوذرات افزایش یافت، به طوری که در تیمار 10 درصد نانوذره به سه برابر تیمار شاهد رسید. غلظت کادمیم در شکل های تبادلی و باقی مانده با تغییر درصد نانوذرات تغییرات چندانی نداشت. همچنین، تحرّک و فراهمی زیستی کادمیم در خاک در تیمار 10 درصد نانوذره، 17 درصد کاهش یافت. بنابراین، می توان نتیجه گیری کرد که نانوذرات مگنتیت تثبیت شده باعث کاهش حلالیت کادمیم در خاک و کاهش فراهمی زیستی این فلز می گردد.

کلیدواژه‌ها

• آلودگی خاک
• عصاره گیری دنباله ای
• فلز سنگین
• نانوذرات

عنوان مقاله [English]

Cadmium Immobilization in Soil using Sodium Dodecyl Sulfate Stabilized Magnetite Nanoparticles

نویسندگان [English]

• Ahmad Farrokhian Firouzi ¹
• Mohammad javad Amiri ²
• Hosein Hamidifar ³
• Mehdi Bahrami ²

¹ Shahid Chamran University

² Fasa University

³ Shiraz University

چکیده [English]

Introduction Some methods of contaminated soils remediation reduces the mobile fraction of trace elements, which could contaminate groundwater or be taken up by soil organisms. Cadmium (Cd) as a heavy metal has received much attention in the past few decades due to its potential toxic impact on soil organism activity and compositions. Cadmium is a soil pollutant of no known essential biological functions, and may pose threats to soil-dwelling organisms and human health. Soil contamination with Cd usually originates from mining and smelting activities, atmospheric deposition from metallurgical industries, incineration of plastics and batteries, land application of sewage sludge, and burning of fossil fuels. Heavy metal immobilization using amendments is a simple and rapid method for the reduction of heavy metal pollution. One way of the assessment of contaminated soils is sequential extraction procedure. Sequential extraction of heavy metals in soils is an appropriate way to determine soil metal forms including soluble, exchangeable, carbonate, oxides of iron and manganese, and the residual. Its results are valuable in prediction of bioavailability, leaching rate and elements transformation in contaminated agricultural soils.
Materials and Methods The objective of this study was to synthesize magnetite nanoparticles (Fe3O4) stabilized with sodium dodecyl sulfate (SDS) and to investigate the effect of its different percentages (0, 1, 2.5, 5, and 10%) on the different fractions of cadmium in soil by sequential extraction method. The nanoparticles were synthesized following the protocol described by Si et al. (19). The investigations were carried out with a loamy sand topsoil. Before use, the soil was air-dried, homogenized and sieved (

کلیدواژه‌ها [English]

• Cadmium
• Soil Contamination
• Sequential Extraction
• Nanoparticles

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