Soil science
Fatemeh Nooralivand; A. Farrokhian Firouzi
Abstract
Introduction Wind erosion is one of the important processes of soil degradation in arid and semi-arid regions. Increased soil surface resistance is a key factor to prevent wind erosion. Mulch can increase the resistance of soil surface against erosive agents by creating a coating on the soil surface. ...
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Introduction Wind erosion is one of the important processes of soil degradation in arid and semi-arid regions. Increased soil surface resistance is a key factor to prevent wind erosion. Mulch can increase the resistance of soil surface against erosive agents by creating a coating on the soil surface. The effectiveness of mulch on wind erosion control is on the quantity, type, and durability of the used in dust sources of Iran for stabilizing soil surface against wind erosion. In recent decades, petroleum mulch has been broadly used for stabilizing soil surface against wind erosion in dust sources of Iran. Bio-polymers (e.g. cellulose hydrogel and biochar) and naturally accessible materials (e.g. nanoclay) as environment-friendly mulches can be an alternative to chemical polymers and petroleum mulches. In arid and semi-arid regions, wetting-drying cycles play a crucial role in soil aggregate formation and strength. However, there have been limited studies assessing the impact of wetting-drying cycles on the durability of applied mulches. The main objective of this study was to assess the effectiveness of different types of mulches, including inorganic montmorillonite nanoclay, chemical polyvinyl acetate polymer, and biological biochar and cellulose hydrogel, at various time intervals. The study aimed to improve the physical and mechanical properties of soil, as well as control wind erosion in a loamy sand soil using a wind tunnel. Additionally, the durability of these mulches was evaluated over time after subjecting them to four wetting-drying cycles.Materials and Methods A factorial experiment was conducted based on completely randomized design with three replications. The factors including mulch type (four levels: nanoclay montmorillonite, polyvinyl acetate polymer, biochar and cellulose hydrogel), mulch concentration (Nanoclay montmorillonite: 0, 16 and 32, Polyvinyl Acetate polymer: 0, 8, and 16, biochar and cellulose hydrogel: 0, 65 and 200 g/m2) and duration (21, 42, 63 and 126 days). The soil used in the wind tunnel experiments was collected from a dust source in the southeast of Ahvaz (Site Number 4). Trays measuring 50×30×5 cm were filled with this soil. The soil surface was then uniformly sprayed with an emulsion of Nanoclay and Polyvinyl Acetate. Additionally, biochar and cellulose hydrogel were mixed uniformly with the soil. Water was sprayed on the soil surface to maintain a constant moisture content of 75% of field capacity. After a specified period, soil properties such as mean weight diameter of aggregates, fractal dimension, penetration resistance, and shear strength were measured. The trays were then placed in a wind tunnel, and a wind erosion test was conducted at a wind speed of 20 m/s for a duration of 5 minutes. The amount of soil loss was measured using the weight method. Then, at each time, the best treatment from each mulch (in terms of reducing wind erosion) was selected and subjected to wet and dry cycles (four cycles).Results and Discussion The results showed a significant interaction effects (p<0.01) of mulch type, mulch concentration and time factors on soil aggregate stability and fractal dimension, penetration resistance, shear strength were significant (p<0.01). Soil loss decreased in soils amended with biochar and cellulose hydrogel and increased in the case of montmorillonite and polyvinyl acetate polymer over the time. The amount of soil loss in soil amended with cellulose hydrogel decreased by 99.3%. The highest amount of soil penetration resistance and shear strength was observed in cellulose hydrogel mulch at the fourth time which were equal to 1038 and 123 kPa, respectively. Over time, the mean weight diameter of aggregates increased in the soil treated with cellulose and biochar hydrogels, but decreased in the polyvinyl acetate and montmorillonite nanoclay treatments. There was a negative correlation between aggregate stability and the fractal dimension of aggregates. In terms of soil loss, at the fourth measurement time, soils modified with cellulose hydrogels, biochar, polyvinyl acetate, and montmorillonite nanoclay experienced reductions of 99%, 71%, 84%, and 85% respectively, compared to the control. After four wet and dry cycles, the soil loss further decreased by 98%, 64%, 76%, and 81% in the respective treatments, compared to the control.Conclusion In general, it can be concluded that cellulose hydrogel presented the greatest effect on reducing soil loss and controlling wind erosion. In the soils amended with biochar and cellulose hydrogel, the effect of mulches on reducing soil loss increased over the time. However, the opposite results were found in the case of polyvinyl acetate and montmorillonite nanoclay polymers. Therefore, biochar and cellulose hydrogel in the long term and polyvinyl acetate polymer and montmorillonite nanoclay in the short term can control wind erosion. Wet and dry cycles at all durations increased soil loss. But their effect remained on soil loss reduction until the end of the fourth cycle. The results revealed that environmentally friendly biopolymers synthesized from biomass components can be considered as sustainable sources to reduce wind erosion. Bio-polymers are a new window into the use of sustainable biomaterials instead of synthetics in wind erosion control.
H. Lohrasbi; A. Farrokhian Firuzi
Abstract
Introduction: Wind erosion is one of the most important environmental challenges in arid and semiarid regions which cause soil loss and dust storm. In recent decades, the potential of soil erosion has been recognized as serious threat against soil sustainability. In addition, accelerated soil erosion ...
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Introduction: Wind erosion is one of the most important environmental challenges in arid and semiarid regions which cause soil loss and dust storm. In recent decades, the potential of soil erosion has been recognized as serious threat against soil sustainability. In addition, accelerated soil erosion has led to harmful environmental effects. Therefore, focus on soil erosion outcomes is necessary in order to mitigate its environmental impacts. Understanding interactions between land use management and topographical properties of landscape are important in order to effectively control soil erosion through implementing best management practices (BMPs). Application of mulch is one of the most prevailing scenarios to prevent the erosive soil against wind as an erosive factor in the hotspots. In this regard the type of much is really important because the environmental aspects and the mulch consistency are important factors for production and selection of mulch between several options. Nowadays, sustainable management is one of the most important scopes in order to achieve the aims of human healthy. In this regards the Bagasse of sugarcane and Conocarpus were selected as feedstocks to produce biochars. Biochar is the by-product of anaerobic process which called pyrolysis. The biogases, energy and so on are other outputs of pyrolysis. Another treatment which evaluated in this study was Zeoplant. Zeoplant is a super absorptive material which is able to hold the water in the soil therefore is capable to enhance the water holding capacity of the soil.
Materials and Methods: In this study the effects of biochar of Bagasse from sugarcane, biochar of Conocarpus and Zeoplant in three levels (0, 2 and 4 percentage) and two moisture levels (25 and 50 percentage of FC) and 3 replications in randomized completely design with factorial on physical and mechanical properties of soil as indices of soil erodibility was studied. Soil sampling accomplished from Horalazim marshes and after application of treatment, incubated in tray with the size of 70×30×10 cm for 90 days. After incubations the trays located in wind tunnel in order to simulate wind erosion process under a wind with 15 m/sec speed and 2 m from soil surface. The main measured soil physical and mechanical parameters include mean weight diameter (MWD), penetration resistance (PR), tensile strength (TS), friability index (FI), shear strength, crusting index (CI), soil textural index and organic matter. The statistical analysis was performed using SAS 9.2 software and the mean comparison was accomplished with Duncan test (5 %). In order to draw the graphs Origin 2017 software was used.
Results and Discussion: The soil texture was silty loam (SiL) including 62% silt, 26% clay and 12% sand, therefore the soil was sensitive to wind erosion. Soil organic matter before application of biochars and Zeoplant was around 1.93% and after application increased to 3.78%. Application of these treatments and the period of incubation, enhanced the soil porosity. Generally increasing soil organic matter and soil porosity and decreasing of bulk density are the main factors to increase the soil aggregation. Our results showed that all three treatments in two moisture levels significantly increased soil porosity, tensile strength and field capacity and decrease soil crusting index (P<0.01). Biochar of bagasse and Zeoplant (2%) also significantly increased shear strength whereas biochar of Conocarpus has no significant effect on shear strength. Overall the applied treatments with armoring effect (AE) and increase the soil aggregate stability, diminished the wind erosion.
Conclusion: Our study illustrated that application of biochar is able to improve soil physical and mechanical properties. The main aspect of this positive effect is the specific characteristics and the structure of biochar which showed with SEM (Scanning electronic microscope) images. Moreover, Zeoplant is organic-inorganic treatment and including high potential to absorb the water in the soil. Indeed, the mulching is an effective management strategy to maintain and preserve the soil against wind (as erosive agent) however afterwards a vegetation cover must be grow on the surface. Therefore some treatments such as Zeoplant are essential to hold the water in the soils of arid and semiarid regions because in those areas the water scarcity is one of the main challenges. Based on our results and evaluation of these treatments we found two main processes which are effective to mitigate wind erosion. The first is aggregation process because of organic carbon and organic matter in the soil and the binding between organic and inorganic components. The second one is an armoring effect which is originating from amendments especially biochar lumps on the surface. Finally our results confirmed the application of evaluated treatments to preserve the erosive soil against wind.
Arsalan Sadeghian; gholamabbas sayyad; Ahmad Farrokhian Firouzi; Mojtaba Norouzi Masir
Abstract
Introduction: Soil is one of the renewable natural resources that take a long time to get renewed; its destruction or conservation depends on how land is used and managed. Soil quality refers to soil capacity in maintaining biological fertility, sustainability in plant production and yield. Maintaining ...
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Introduction: Soil is one of the renewable natural resources that take a long time to get renewed; its destruction or conservation depends on how land is used and managed. Soil quality refers to soil capacity in maintaining biological fertility, sustainability in plant production and yield. Maintaining soil quality is essential for sustainable food production and decomposition of organic wastes. Different agronomic managements have various effects on soil quality indicators. There are few published researches about the effect of various agronomic managements on soil quality indices in arid and semi-arid regions (such as Iran). Therefore, this study was conducted to investigate and compare the effects of three different agronomic management including crop rotation-crop residue removal, monoculture-crop residue removal and monoculture-crop residue retention systems on some physical indicators of soil quality.
Materials and Methods: In this research, three farms with three crop management systems including crop rotation-crop residue removal, monoculture-crop residue removal and monoculture-crop residue retention (10 ton per hectare) systems were investigated. In the monoculture-crop residue removal treatment, wheat was continuously cultivated for 8 years. In the rotation-crop residue removal system, wheat - mung bean were cultivated in rotation for 2 years. For the monoculture-crop residue retention system, wheat was planted for 10 years, after which the post-harvest residues were mixed with topsoil (0-15 cm). One hundred twenty soil samples (40 samples from each field) were prepared by systematic sampling from 0 to 15 cm depth. In order to investigate the effect of different agronomic management on soil physical quality, some indicators including soil organic matter, total porosity, bulk density, mean weight diameter of aggregates, aggregate stability, available water capacity, penetration resistance, saturated hydraulic conductivity, and slope of retention curve at inflection point (S-index) were measured. The experiment was conducted in a randomized complete block design with four replications. Also, the mean comparison was performed using Duncan's multiple range test.
Results and Discussion: The results of analysis of variance showed that the type of crop management had a significant effect (p<0.01) on organic matter, total porosity, bulk density, mean weight diameter of aggregates, aggregate stability, available water capacity, penetration resistance, saturated hydraulic conductivity and S-index. The results of mean comparison indicated that the monoculture-crop residue removal system resulted in a significant increase in bulk density (1.31 g cm-3) and soil penetration resistance (0.4 MPa) than other systems, while the highest organic matter content (1.038 %), porosity (55.7%), mean weight diameter (1.04 mm), aggregate stability index (28%), available water capacity (0.15%), saturated hydraulic conductivity (46.17 cm h-1) and S-index (0.053) was observed in the monoculture-crop residue retention system. The most measured values for soil quality indicators were more in monoculture-crop residual retention system compared with the other treatments. The amount of S-index of soils under monoculture-crop residual retention, crop rotation-crop residues removal, and monoculture-crop residual removal systems were 0.053, 0.032 and 0.019, respectively. The high S-index value of soil under monoculture-crop residual retention system can be attributed to its suitable amount of soil organic carbon and better soil structural quality. By contrast, in monoculture-crop residue removal system, elimination of organic matter had undesirable effect on soil porosity, and aggregate stability. Furthermore, the S-index values of the soils under crop rotation-crop residues removal, and monoculture-crop residual removal systems are below the Dexter’s soil quality index threshold (0.035); therefore, the results indicated that the soils are degraded.
Conclusion: The results of this study showed that crop management plays an important role in changing soil physical quality indicators. Among the studied crop managements, monoculture-crop residue retention management system showed more positive effects on soil physical parameters than the others. Retention of crop residues on soil surface increases the soil organic matter which in turn has positive effects on soil properties such as aggregate stability, saturated hydraulic conductivity, available water content and slope of retention curve at the inflection point. On the other hand, the monoculture-crop reside removal treatment, with less soil organic matter, had more undesirable effects on agronomic soils than other treatments. Based on the results, the effect of different agronomic management systems on improving soil physical quality indexes was in the following order: monoculture-crop residue retention >crop rotation-crop residue removal > monoculture-crop residue removal. According to the results, it can be concluded that soil organic matter is the central index of soil quality, which is intensely influenced by crop management system. Therefore, in arid and semiarid areas such as Iran, monitoring of the long-time effect of agronomic management on status of soil organic matter and soil physical indices is urgent.
Mohammad Taghi Kouhiyan Afzal; Ahmad Farrokhian Firouzi; Mehdi Taghavi
Abstract
Introduction: Nowadays pollution of sand columns and water resources with hexavalent chromium is enhancing due to the increase of industrial and agricultural activities. In recent years nanoscale zerovalent iron particles (nZVIP) have been used according to special properties comprising of high surface ...
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Introduction: Nowadays pollution of sand columns and water resources with hexavalent chromium is enhancing due to the increase of industrial and agricultural activities. In recent years nanoscale zerovalent iron particles (nZVIP) have been used according to special properties comprising of high surface area, high reaction sites, non-toxic, non-expensive and high potential for removal of pollutants such as hexavalent chromium from sand columns and water. The size range of Zerovalent iron nanoparticles is less than 100 nm. So they could potentially be transported into the subsurface and finally be mixed with the target pollutants. Chromium is one of the steely-grey, lustrous and toxic heavy metals with high toxicity potential. Upon chromium (VI) toxicity this element is classified as a primary contaminant. Chromium (III) compounds is not toxic and hazardous and are grouped as one of the beneficial elements for human and other animals, while the toxicity and carcinogenic properties of hexavalent chromium have been realized for a long time in all over the world. Application of polymers as nZVIP stabilizers diminishes flocculation and sedimentation of nanoparticles. So usage of such polymers may lead to decreasing of particle size, enhancing reactivity and increasing particle transport in column and continuous medium studies. The objectives of this study were: (1) synthesis and characterization of different surface modified nZVIP with some polymers including Polyacrylamide (PAM) and Guar gum (GG), (2) the removal of hexavalent chromium ions from sand columns by application of different stabilized nZVIP, (3) investigation the impacts of different experimental situations on hexavalent chromium removal from sand columns including primary nZVIP dosages and primary hexavalent chromium dosages, and (4) evaluation nZVIP transportation in sand columns.
Material and Methods: In this research, nZVIP were synthesized using chemical reduction of ferrous sulfate by sodium borohydride. Guar gum (GG) as a green and environmentally friendly coating and polyacrylamide (PAM) as an anionic and biodegradable polymer were applied for stabilizing of nanoparticles. Zeta potential values were determined by a ZetaPlus zeta-potential analyzer from Brookhaven Instruments Corporation and the measured values were gathered from a suspension containing 5 mg zero valent iron nanoparticles in 100 mL of 1 mM NaCl solution, at room temperature. The hydrodynamic diameter of nanoparticles was determined using a ZetaPlus zeta potential analyzer and the Brownian movement of particles was related to nanoscale zerovalent iron particles hydrodynamic diameter. The morphology of zerovalent iron nanoparticles was determined by scanning electron microscope (SEM). Furthermore, the size of the synthesized nanoparticles was considered using a transmission electron microscope (TEM) via image measuring software.
Results and Discussions: The results showed by increasing of nanoparticle and hexavalent chromium dosage the removal efficiency of chromium increased and decreased from sand columns, respectively. Increasing of hexavalent chromium dosage from 40 to 80 mg/L in sand columns lead to more excessive chromium ions at sand columns and diminishing of hexavalent chromium removal efficient from sand particles. When the dosage of nanoscale zerovalent iron particles raised from 1 to 3 g/L and while the concentration of Cr (VI) was on a constant value of 100 mg/L, the effective reaction sites for hexavalent chromium removal would increase and so the removal performance would enhance according to the nanoparticle dosages. The findings of the current study also revealed when ionic strength and nZVIP dosage enhanced, the transportation of nZVIP decreased in sand columns. By enhancing the concentration of nZVIP, the surface reaction sites of nZVIP increased and hence the efficiency of chromium removal raised from sand columns.
Zeta potential is a good parameter for evaluating the colloidal stability. This parameter is an index of stability that reflects the electrostatic repulsion forces between charged particles. By shifting the zeta potential values to the higher records (more negative) the magnitude of repulsion forces among the particles will increase and the stability of them will enhance as a result. In this research the achieved zeta potential records for synthesized nZVIP showed that PAM-stabilized nZVIP and non-stabilized nZVIP had the most and the least stability values respectively.
Conclusion: The final results of this study revealed that increasing dosages of synthesized zerovalent iron nanoparticles enhanced the removal efficiency of nitrate and hexavalent chromium from sand columns. When dosages of Cr (VI) increased the removal efficiency of current pollutants decreased. TEM results showed the order of particle sizes were upon to the following trend: PAM-nZVIP < GG- nZVIP < Bare- nZVIP. So PAM stabilized zerovalent iron nanoparticles and the bare nanoparticles were the smallest and largest sizes of all. The efficiency of hexavalent chromium removal and nanoparticle transormation were according to the following trend: polyacrylamide (PAM)- nZVIP> Guar gum (GG)- nZVIP> Bare- nZVIP
F. Arzaghi; A. Farrokhian Firouzi; N. Enayatizamir; B. Khalilimoghaddam
Abstract
Introduction: Wind erosion is the most important agent of environmental degradation, poverty of soil, air pollution and the dust spread. Wind erosion is causing a lot of damage to crops, buildings, facilities and vehicles. The first step of the wind erosion control is the stabilization of soil particles. ...
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Introduction: Wind erosion is the most important agent of environmental degradation, poverty of soil, air pollution and the dust spread. Wind erosion is causing a lot of damage to crops, buildings, facilities and vehicles. The first step of the wind erosion control is the stabilization of soil particles. Soil stabilizing methods to control wind erosion can be classified into mechanical, biological and chemical stabilization. Mechanical soil stabilization type is relatively time-consuming and costly. Biological stabilization is a traditional way that exhibits a long-term validity but sandy soil cannot provide essential water and nutrition elements needed by plant. Recently, chemical stabilization such as high-molecular-weight anionic polyacrylamide (PAM) has attracted the attention of researchers because of its advantages in easy and quick construction, and the improvement of the growing conditions for plant. However PAM has been mainly used to control water erosion and there is still little available information regarding the effectiveness of PAM on preventing soil loss by wind erosion. The main objective of this study was to investigate the feasibility of using PAM in wind erosion controlling. Also, effects of PAM on some soil physical and chemical properties and their temporal variability were evaluated.
Materials and Methods: In this study polyacrylamide polymer was used as a restoration of soil and soil structure stabilizer on sandy soil of Azadegan Plain (Khuzestan province, Iran). Consequently, an experiment was conducted as factorial based on completely randomized design with three replicates. The experimental treatments were consist polyacrylamide polymer (PAM) at three levels (0, 0.5, and 1 %), soil moisture at two levels (80% FC and dry) and time duration at three levels (15, 30 and 45 days). The emulsion of PAM was sprayed homogeneously on the soil surface. After passing each time treatment, penetration resistance and some physical and chemical properties of soil was measured. Finally after doing all measurements, the treatment with maximum penetration resistance were selected and the sample was prepared for wind tunnel testing. The wind erosion experiments were conducted in a wind tunnel. Soil samples were located in removable trays. The width and length of the trays was 30 and 100 cm, respectively. The wind erosion experiments were performed under wind velocity of 12 m s−1 according to the actual situation of study area.
Results and Discussion: The results indicated that in comparison to control, soil acidity decreased at both levels of the polymer with increasing time. The decreasing of soil acidity in wet treatments was more than dry treatment. The lowest amount of pH was obtained in the 30-day wet treatment at 1% polymer level. The results show from the 30th day onwards, soil pH increased, which is probably due to the polymer degradation. With passing time, soil electrical conductivity (EC) at both levels of the polymer (0.5 and 1%) increased and decreased respectively after 30 days. These observations are probably because after 30 days the properties of polymer-hydrophilic units gradually decrease and water adsorption was reduced or that soil soluble salts were adsorbed by polymer particles. The results also showed with passing time, Mean Weight-Diameter of Soil Aggregates (MWD) increased and then after 30 days declined. The largest MWD was observed in 30 days treatment at 1% polymer level. After thirty days, its effect has probably diminished due to polymer degradation. Furthermore, the results showed no significant difference of bulk density among treated soil with different level of polymer, but application of polymer caused to decrease bulk density comparison to control. Polymer application increased soil penetration resistance significantly. Using 1% of polymer increased it to 6 kg/m2. The results also indicated that the soil resistance at first increased with time and then decreased significantly. The amount of soil penetration resistance at 45-day was less than 15-day. The results of wind tunnel with a maximum 12 m/s wind velocity showed that application of the polymer reduced the erosion of sands samples to zero.
Conclusion: The research results indicated that PAM application increased soil penetration resistance and MWD. The polymer could improve the structure of soil aggregates and increase the amount of dry-stable aggregates and therefore decrease soil bulk density. Spraying PAM solution on the surface of soil significantly decreased the wind erosion amounts. Therefore, this inexpensive and easily usable polymer can be considered as a soil stabilizer to control wind erosion in arid and semiarid areas.
Ahmad Farrokhian Firouzi; Mohammad javad Amiri; Hosein Hamidifar; Mehdi Bahrami
Abstract
Introduction Some methods of contaminated soils remediation reduces the mobile fraction of trace elements, which could contaminate groundwater or be taken up by soil organisms. Cadmium (Cd) as a heavy metal has received much attention in the past few decades due to its potential toxic impact on soil ...
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Introduction Some methods of contaminated soils remediation reduces the mobile fraction of trace elements, which could contaminate groundwater or be taken up by soil organisms. Cadmium (Cd) as a heavy metal has received much attention in the past few decades due to its potential toxic impact on soil organism activity and compositions. Cadmium is a soil pollutant of no known essential biological functions, and may pose threats to soil-dwelling organisms and human health. Soil contamination with Cd usually originates from mining and smelting activities, atmospheric deposition from metallurgical industries, incineration of plastics and batteries, land application of sewage sludge, and burning of fossil fuels. Heavy metal immobilization using amendments is a simple and rapid method for the reduction of heavy metal pollution. One way of the assessment of contaminated soils is sequential extraction procedure. Sequential extraction of heavy metals in soils is an appropriate way to determine soil metal forms including soluble, exchangeable, carbonate, oxides of iron and manganese, and the residual. Its results are valuable in prediction of bioavailability, leaching rate and elements transformation in contaminated agricultural soils.
Materials and Methods The objective of this study was to synthesize magnetite nanoparticles (Fe3O4) stabilized with sodium dodecyl sulfate (SDS) and to investigate the effect of its different percentages (0, 1, 2.5, 5, and 10%) on the different fractions of cadmium in soil by sequential extraction method. The nanoparticles were synthesized following the protocol described by Si et al. (19). The investigations were carried out with a loamy sand topsoil. Before use, the soil was air-dried, homogenized and sieved (
Ahmad Farrokhian Firouzi; Hosein Hamidifar; Mohammad javad Amiri; Mehdi Bahrami
Abstract
Introduction: Nanoparticles due to their large specific area and reactivity recently have been used in several environmental remediation applications such as degradation of organic compounds and pesticides and adsorption of heavy metals and inorganic anions. Because of concern over potential threats ...
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Introduction: Nanoparticles due to their large specific area and reactivity recently have been used in several environmental remediation applications such as degradation of organic compounds and pesticides and adsorption of heavy metals and inorganic anions. Because of concern over potential threats of nanoparticle releases into the soil–water environment, a number of studies have been carried out to investigate the transport, retention and deposition of nanoparticles in saturated porous media. Many of these studies are based on measurements of transport in columns packed with idealized porous media consisting of spherical glass beads or sand. The nanoparticles are usually introduced into the column and breakthrough curve concentrations are measured at the column outlet. To examine the effect of various parameters on the transport of nanoparticles in porous medium, for convenience, all the parameters considered the same in the experiments, and only one parameter in the experiments is changed and investigated.
Materials and Methods: The objective of this research is quantitative study of modified magnetite nanoparticles transport in saturated sand-repacked columns. The modified magnetite nanoparticles with Sodium dodecyl sulfate were synthesized following the protocol described by Si et al. (2004). The experimental setup included a suspension reservoir, Teflon tubing, a HPLC pump, and a glass column (2.5 cm i.d. and 20 cm height). Therefore, breakthrough curves of modified magnetite nanoparticles with Sodium dodecyl sulfate and chloride were determined under saturated conditions and influence of nanoparticles concentration (0.1 and 0.5 g.L-1) and pore velocity (pressure head of 2 and 10 cm) on nanoparticles transport were investigated. For each medium bed, the background solution were first pumped through the column in the up-flow mode to obtain a steady flow state. Then, a tracer test was conducted by introducing CaCl2 solution into the column. The response curve was followed by analyzing the concentration history of Cl-1 in the effluent. Then, the influent was switched back to the background solution to thoroughly elute the tracer. Following the tracer test, a modified magnetite nanoparticles with sodium dodecyl sulfate was introduced into the column and the nanoparticle breakthrough curves were obtained by measuring the concentration history of total Fe in the effluent. Total iron concentration was analyzed with a flame atomic-absorption spectrophotometer.
One site and two site kinetic attachment-detachment models in HYDRUS-1D software were used to predict the nanoparticles transport. Also parameters of model efficiency coefficient (E), root mean square error (RMSE), geometric mean error ratio (GMER), and geometric standard deviation of error ratio (GSDER) were used to determine the accuracy of the models.
Results and Discussion: SEM measurements demonstrated that the particle size of nanoparticles was about 40-60 nm. The hydrodynamic dispersion coefficient (D) for each medium was obtained by fitting the classic 1-D convection–dispersion equation (CDE) to the experimental breakthrough data using the CXTFIT code (STANMOD software, USDA). The relative concentration of nanoparticles in comparison with chloride in the collected effluent from soil columns were much lower indicating a strong retention of nanoparticles in studied porous media, thereby attachment, deposition and possibly straining of nanoparticles.
Modeling results showed that in all sites of both models (one site and two-site kinetic attachment-detachment models), attachment was rapid and detachment was slow. These attachment kinetic sites may be because of consistent charges of minerals with attachment. Therefore, considering to same attachment-detachment behavior in two sites of two-site kinetic model, it is concluded that the one site kinetic model had eligible estimation of nanoparticles breakthrough curve in the studied sandy soil columns lonely. Efficiency of one site and two-site models varied from 0.761 to 0.851 and 0.760 to 0.846 respectively that indicated both models had good estimation of nanoparticles transport in the sandy soil. Also, logarithmic form of nanoparticles breakthrough curve showed that both models had good estimation of all ranges of breakthrough curve containing its tail.
Conclusion: Investigation of transport modeling of modified magnetite nanoparticles with Sodium dodecyl sulfate in a saturated sandy soil showed that decreasing the nanoparticles concentration would enhanced the mobility of modified magnetite nanoparticles, but increasing of pressure head had no effect on nanoparticles mobility. The results of models evaluation showed that both one site and two-site models had eligible estimation of nanoparticles transport in the studied sandy soil columns.
F. Nooralivand; A. Farrokhian Firouzi; A. Kiasat; M. Chorom; A. Akbar Babaei
Abstract
Introduction: During the recent decades, the use of N fertilizers has undeniable development regardless of their effects on the soil and environment. Increasing nitrate ion concentration in soil solution and then, leaching it into groundwater causes increase nitrate concentration in the water and raise ...
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Introduction: During the recent decades, the use of N fertilizers has undeniable development regardless of their effects on the soil and environment. Increasing nitrate ion concentration in soil solution and then, leaching it into groundwater causes increase nitrate concentration in the water and raise the risk suffering from the people to some diseases. World health organization recommended maximum concentration level for nitrate and nitrite in the drinking water 50 and 3 mg/l, respectively. There are different technologies for the removal of nitrate ions from aqueous solution. The conventional methods are ion exchange, biological denitrification, reverse osmosis and chemical reduction. Using nanoscale Fe0 particles compared to other methods of nitrate omission was preferred because of; its high surface area, more reactive, lower cost and higher efficiency. More studies on the reduction of nitrate by zero-valent iron nanoparticles have been in aqueous solutions or in the soil in batch scale. Nanoparticles surface modified with poly-electrolytes, surfactants and polymers cause colloidal stability of the particles against the forces of attraction between particles and increases nanoparticle transport in porous media. The objectives of this study were to synthesize carboxymethyl cellulose stabilized zero-valent iron nanoparticles and consideration of their application for nitrate removal from sandy soil.
Materials and Methods: The nanoparticles were synthesized in a lab using borohydride reduction method and their morphological characteristics were examined via scanning electron microscopy (SEM), X-ray diffraction (XRD) and Fourier Transmission Infrared Spectroscopy (FTIR). Experiments were conducted on packed sand column (40 cm length and 2.5 cm inner diameter) under conditions of different nanoparticle concentration (1, 2, and 3 g1-1)and high initial NO3- concentration (150, 250, and 350 mgl-1). Homogeneous soil column was filled with the wet packed method. CMC-NZVI suspensions of nanoparticle in aqueous solution (0.01 M CaCl2 and 0.001MKCl) were pumped into the sand column during the injection of nitrate solution. During transport experiment, the flask containing CMC-ZVIN suspension was sonicated using a 50 KH ultrasonicator (DSA100-SK2) to prevent particle agglomeration and ensure homogeneity of the suspensions. In these experiments pore water velocity was 0.16 mms-1. Nitrate and Nitrite concentrations in the samples were measured using UV-VIS.HACH DR 5000 spectrophotometer at wavelengths 220 and 530nm, respectively, and ammonium concentration was measured by Kjeldahl method. All chemicals used in this research were of chemical grades and all solutions were prepared using deionized water (DI).
Results and Discussion: Effect of nanoparticles and nitrate concentration on nitrate reduction by stabilized nanoparticle in sand column was investigated. The Results of study indicating at the first of reaction in both cases rate and amount of nitrate reduction was increased gradually. But over time, due to saturation capacity of nanoparticles at higher concentrations of nitrate, reduction speed and amount of reduction was constant approximately. The result showed that increasing dosage of nanoparticles and decreasing the influent nitrate concentration would increase percentage of nitrate reduction. Maximum percentage of reduction (82.56%) were observed at nanoparticles concentration=3 gl-1 and high initial nitrate concentration=150 mgl-1 and minimum percentage of reduction (63.94%) were observed at nanoparticles concentration=1 gl-1 and high initial nitrate concentration=150 mgl-1. After the end of experiment time, amount of observed ammonium and nitrite was a few in the drainage water of sand column. During the reaction nitrate reduction by nano-particles, H + was used and OH- was produced therefore through reaction, environment pH increased continuously. In conditions of alkaline, ammonium release in the form of N2. Therefore reduction of the amount of ammonium may due to high pH of environment reaction or fixation of ammonium in the surface colloidal of particles in porous medium. Nitrite is an intermediate product and due to the reaction conditions can be converted to ammonia or nitrogen gas. The final product of reduction would be nitrogen gas, and produced nitrite and ammonium was less than 2%.
Conclusion: The results indicate that, in all experiments (effect of nanoparticle and nitrate concentration on nitrate reduction), amount of observed ammonium and nitrite was a few in the drainage water of sand column and most of the nitrate converted to nitrogen gas. Since maximum concentration level of ammonium in drinking water is 50 times less than nitrate concentration, nitrogen gas is an ideal product in water treatment process. Carboxymethyl cellulose prevents agglomeration ZVI nanoparticles and enhanced the reactivity and transport of nanoparticle in the porous media. The findings of this research demonstrated that carboxymethyl cellulose-stabilized zero-valent iron nanoparticles have a high potential for reduction of nitrate in aqueous solutions and porous media. Therefore, it can be used as an effective method for removing nitrate from water.
A. Farrokhian Firouzi; M. Homaee; E. Klumpp; R. Kasteel; M. Sattari
Abstract
Abstract
Microbial contaminants transport to groundwater is a serious environmental problem that can result in large outbreaks of waterborne diseases. Some of bacteria can travel from vadose zone and cause contamination of groundwater resources. Thus, an accurate prediction of transport and fate of ...
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Abstract
Microbial contaminants transport to groundwater is a serious environmental problem that can result in large outbreaks of waterborne diseases. Some of bacteria can travel from vadose zone and cause contamination of groundwater resources. Thus, an accurate prediction of transport and fate of pathogenic microorganisms in unsaturated soil is needed to protect groundwater resources. The main objectives of this research were quantitative study of bacterial transport and deposition under unsaturated conditions in calcareous soils. A series of column leaching experiment with well-controlled suction and flow rate was conducted. Breakthrough curves (BTCs) of Pseudomonas fluorescens and Cl were measured. After the leaching experiment the bacteria was measured in difference layers of the soil columns. The HYDRUS-1D kinetic attachment-detachment model (AD) was used to evaluate the transport and deposition of bacteria in soil columns. The breakthrough curves in soils were described well by attachment-detachment model. Whereas the model fit underestimate the amount of bacteria retention in the soil columns. The detachment rate was less than 0.001 of the attachment rate, indicating irreversible attachment of bacteria. Most of the cells were retained close to the soil column inlet, and the rate of deposition decreased with depth. Microbial reduction rate for the soil was 10.18-13.34 log m-1. High reduction rate of bacteria was attributed to soil calcium carbonate that has favorable attachment site for bacteria.
Keywords: Bacteria transport, Pseudomonas fluorescens, Calcareous soil, Bacteria Attachment, Unsaturated flow, Bacteria Detachment