Sh. Haghighi; Z. Sharifi
Abstract
Introduction: Calcareous soils are described as soils containing quantities of calcium carbonate which have an enormously effect on the soil properties (physical, consisting of soil water relations and soil crusting, or chemical consisting of the availability of plant nutrients) and plant growth. Calcareous ...
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Introduction: Calcareous soils are described as soils containing quantities of calcium carbonate which have an enormously effect on the soil properties (physical, consisting of soil water relations and soil crusting, or chemical consisting of the availability of plant nutrients) and plant growth. Calcareous soils arise clearly in arid and semi-arid areas due to rare precipitation and little leaching. It has been evaluated that these soils contain over one-third of the world's surface zone and their CaCO3 content ranged from a few to 95%. Calcareous soils faced many challenges such as shortage of organic matter, low structure stability, low water holding capacity, low CEC, high pH, surface crusting and cracking and great infiltration rate which cause loss of essential plant nutrients via leaching or deep percolation. Another problem in calcareous soils is low availability of plant nutrients particularly phosphorous and micronutrients specially zinc, iron and manganese, and a nutritional imbalance between elements such as potassium, magnesium and calcium. Although a calcareous soil is dominated by free lime, it could also incorporate large quantities of iron, aluminum, and manganese. These metals provide more strong sorption sites for phosphorus and are mostly more significant in controlling phosphorus solubility in calcareous soils than calcium carbonate itself. Under such severe conditions, desired yield levels are difficult to attain. Calcareous soils lack the organic matter required for optimal crop yield. Therefore, numerous studies have made efforts to increase the availability of nutrients in the soils through different treatments. Common methods for dealing with these deficiencies, is the use of chemical fertilizers that have the risk of environmental pollution in addition to the high cost and low efficiency. Oxidation of sulfur leads to sulfuric acid formation which can decrease the soil pH and increase dissolution of insoluble soil minerals and release of essential plant nutrients. Furthermore, the addition of organic amendments improves the soil chemical and physical properties, initiates nutrient cycling, and provides a functioning environment for vegetation. Materials and Methods: The objective of this research was to increase solubility of nutrient elements in a calcareous soil considering nine treatments (i.e., control (Blank), Soil + Humic Acid (HA), Soil + Sulfuric Acid (H2SO4 ), Soil + Thiobacillus (T), Soil + Sulphur (Sº), Soil + Sulphur + Thiobacillus (Sº +T), Soil + Vermicompost (VC), Soil + Vermicompost + Thiobacillus (VC+T) and Soil + Sulphur + Vermicompost + Thiobacillus (Sº +VC+T)). The experimental design was factorial arrangement in randomized complete block, with all the treatments replicated three times. All the treatments were incubated under the laboratory condition for 90 days in 25 ± 2 °C and 70% of water holding capacity by distilled water. During the incubation period, the moisture of the samples was kept at 70% FC by daily addition of deionized water based on weight loss. At the end of incubation period the pH value, electrical conductivity (EC), available form of macro elements (K, P and N) and micro elements (Zn, Mn, Fe and Cu) were determined in all treatments by standard methods. Results and Discussion: The results showed that, the soil pH value significantly decreased in Sº+T and Sº+VC+T treatments, in com\pared to the blank. While, the EC of these treatments significantly increased with respect to the blank. The results also showed that most of the treatments have been able to increase the solubility of the nutrients. However, the effect of Sº +VC+T treatment on increasing the availability of studied soil nutrients and decreasing pH value was more significant than the other treatments. Conclusion: Analysis of the results obtained from this study using classical statistic methods showed that applying a single treatment cannot remove all obstacles to increase nutrient availability in calcareous soils. This may be attributed to high buffering capacity of calcareous soils and complexity of factors which control mineral solubility and nutrient availability. While, treatments that simultaneously provide soil organic matter and lower pH (such as Sº+VC+T) can significantly remove barriers to increase nutrient uptake in these soils. As a result, the simultaneous application of organic fertilizers, elemental sulfur and Thiobacillus bacteria can be a promising approach to increase the solubility of nutrients in calcareous soils and to increase the quantitative and qualitative growth of plants in these soils.
Z. Sharifi; Mohammad Taaher Hossaini
Abstract
Introduction: the use of municipal solid waste (MSW) compost in agriculture as a soil conditioner is increasing day by day because of its positive effects on biological, physical, and chemical soil properties. However, some of the composts because of contamination with heavy metals and other impurities ...
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Introduction: the use of municipal solid waste (MSW) compost in agriculture as a soil conditioner is increasing day by day because of its positive effects on biological, physical, and chemical soil properties. However, some of the composts because of contamination with heavy metals and other impurities can have deleterious effects on groundwater quality, agricultural environment, food chain, plant growth and activity of soil microorganisms. Therefore, this study was conducted to investigate the physical and chemical properties, fertilizing potential and heavy metal polluting potential of two types of municipal solid waste composts with processing time between 4 to 8 years (type A) and between1 to 4 years (type B) produced in Sanandaj city with the aim of using it as an organic fertilizer.
Materials and Methods: Sanadaj city, the center of Kurdistan province, with a population of about 335,000 is located in the west of Iran. The current solid waste generation from the city is about 320 t/day, which are not separated at source of generation. About 200 t of the total produced wastes are composted using an open windrows system at the Sanandaj MSW Composting Plant, which is located in 10 km of Sanadaj-Kamiaran road and the rest are disposed at the landfill site. The compost manufactured by the composting plant has been collected around it in two different locations. The first belonges to the product of 2004-2008 (type A) and the second belonges to the product of 2009-2013 (type B). Till now, due to lack of quality information associated with these products, they have remained unused. Therefore, in this study, we sampled 3 samples composed of six subsamples (each containing 2 kg) from the products in March 2013. The samples were analyzed to determine the physical properties (including undesirable impurities, initial moisture content, particle size distribution, particle density, bulk density (ρb), porosity, and maximum water holding capacity), and the chemical properties (including organic carbon, ash content, pH and salinity) and total amounts of N, P, Ca, Mg, K, Na, Mn, Fe, Cr, Zn, Pb, Ni and Cd using standard methods.
Results and Discussion: The results showed that bulk density, ash content, and the amounts of elements based on the dry weight of compost increased with composting time, however particle size decreased. It is well known that dry bulk density increased with composting time as ash content increased and particle size decreased by decomposition, turning and screening. The decreases of particle size with composting time cause an enrichment of metals based on the dry weight of compost. It is likely due to solubilization of metals in waste by organic acid produced during the microbial decomposition of organic matter and their subsequent adsorption on finer particles due to the higher surface area and the higher ion exchangeable capacity. The evaluation of the fertilizing potential of the surveyed composts by comparing their properties with different standard sets showed that the both composts under test in this study were failed to meet the standard permissible limits with regard to glass content (on average, 21.7 times over the permissible limit), gravel content (on average, 1.4 times over the permissible limit), lead content (on average, 1.6 times over the permissible limit), and salinity content (on average, 1.4 times over the permissible limit). Furthermore, compost type B also failed to meet the standard permissible limits with regard to initial moisture content (on average, 1.4 times over the permissible limit) and ρb (0.2 gcm-3, less than permissible limit) for agricultural purposes. The results showed that excessive amount of glass impurity bigger than 2 mm, salinity and lead contents are the major problems in the use of the composts for agricultural purposes. It should be noted that according to the maximum permissible limit of lead (150-300 mg kg-1) for compost C1 quality class described by Australian standard; both the composts can be used as fertilizers or soil amendments. In order to eliminate glass impurity, remediation approaches such as fine milling and pelleting is needed to disguise the residual glasses and render it as relatively harmless. A feasible approach to eliminate these problems is probably physical fractionation of the studied composts. It allows us to assess the distribution of nutrients and contaminants values in the different physical fractions of the composts, which is useful to detect and to eliminate of the particle sizes which are the responsible for these impurities.
Conclusion: The assessment of MSW-based compost for use in agricultural soil as fertilizer or conditioner is a sustainable recycling practice owing to its nutrient content and its positive effects on soil physico-chemical properties. Thus, we evaluated the fertilizing potential of two MSW composts produced in Sanandaj city for agricultural purposes. Altogether, the results of the study showed that excessive amount of glass impurity bigger than 2 mm and salinity were the major problems in the use of the composts for agricultural purpose. As a result, the quality of the surveyed composts was not suitable for agricultural purposes without appropriate remediation of these restrictions.
